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Photolysis of methylcobalamin. Nature of the reactive excited state

Kunkely, Horst and Vogler, Arnd (1993) Photolysis of methylcobalamin. Nature of the reactive excited state. Journal of Organometallic Chemistry 453 (2), pp. 269-272.

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Abstract

Photolysis of methylcobalamin (Co(III)corrin(CH3)L + H2O + O2 �> Co(III)(H2O)L + H2CO + OH-) shows a pronounced wave-length dependence. It is suggested that the reactive excited state is of the ligand-to-ligand charge transfer (LLCT) type and involves the promotion of an electron from the Co-C sigma-bond to a pi*(corrin) orbital. This LLCT transition mixes with the pipi*(corrin) transitions. ...

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Item Type:Article
Date:1993
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1016/0022-328X(93)83121-BDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Universitätsbibliothek Regensburg
Deposited On:21 Dec 2011 06:40
Last Modified:13 Mar 2014 18:19
Item ID:23011
Owner Only: item control page

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