Cartailler, T. and Kunz, Werner and Turq, P. and Bellissent-Funel, M.-C. (1991) Lithium bromide in acetonitrile and water: a neutron scattering study. Journal of Physics: Condensed Matter 3 (47), pp. 9511-9520.
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The structure around lithium ions in solutions of lithium bromide in acetonitrile and water has been studied by neutron diffraction. For this purpose the isotopic first-order difference method has been applied to the lithium ion. For a 0.58 M acetonitrile solution it has been found that the bromide anion enters into the first solvation shell around the lithium ion, whereas in the case of a 1.88 M aqueous solution the first hydration shell of the cation is not disturbed by the anion. The solvation number is approximately 3 in the case of acetonitrile and approximately 4.5 in the case of water.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz|
|Keywords:||lithium bromide acetonitrile aq structure|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||08 May 2012 11:43|
|Last Modified:||08 May 2012 11:43|