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The cooperative dynamics of the H-bond system in 2-propanol/water mixtures: Steric hindrance effects of nonpolar head group

Sato, T. and Buchner, Richard (2003) The cooperative dynamics of the H-bond system in 2-propanol/water mixtures: Steric hindrance effects of nonpolar head group. Journal of Chemical Physics 119 (20), pp. 10789-10800.

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Abstract

We have detd. the complex dielec. spectra of 2-propanol/water mixts. employing time domain reflectometry for the entire mixing range in 0.1≤ν/GHz≤25 at 20 °C, 25 °C, and 30 °C. At the specific concns., a frequency range was expanded up to 89 GHz with the help of waveguide interferometry. The excess activation free energy, ΔGE, enthalpy, ΔHE, and entropy, ΔSE, and their partial molar quantities, ...

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Item Type:Article
Date:2003
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1063/1.1620996DOI
CODEN:JCPSA6Other
Keywords:propanol water mixt hydrogen bond dielec spectra excess activation
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:15 May 2012 13:31
Last Modified:15 May 2012 13:31
Item ID:24350
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