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Dynamics of Imidazolium Ionic Liquids from a Combined Dielectric Relaxation and Optical Kerr Effect Study: Evidence for Mesoscopic Aggregation

Turton, D.A. and Hunger, J. and Stoppa, A. and Hefter, Glenn and Thoman, A. and Walther, M. and Buchner, Richard and Wynne, K. (2009) Dynamics of Imidazolium Ionic Liquids from a Combined Dielectric Relaxation and Optical Kerr Effect Study: Evidence for Mesoscopic Aggregation. Journal of the American Chemical Society 131 (31), pp. 11140-11146.

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Abstract

The authors have measured the intermol. dynamics of the 1,3-dialkylimidazolium-based room-temp. ionic liqs. (RTILs) [emim][BF4], [emim][DCA], and [bmim][DCA] at 25 °C from <1 GHz to 10 THz by ultrafast optical Kerr effect (OKE) spectroscopy and dielec. relaxation spectroscopy (DRS) augmented by time-domain terahertz and far-IR FTIR spectroscopy. This concerted approach allows a more detailed ...

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Item Type:Article
Date:2009
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1021/ja903315vDOI
CODEN:JACSATOther
Keywords:dynamics imidazolium ionic liq dielec relaxation optical Kerr mesoscopic aggregation imidazolium ionic liq
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:15 May 2012 13:10
Last Modified:15 May 2012 13:10
Item ID:24354
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