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Hydration of Formate and Acetate Ions by Dielectric Relaxation Spectroscopy

Rahman, H.M.A. and Hefter, Glenn and Buchner, Richard (2012) Hydration of Formate and Acetate Ions by Dielectric Relaxation Spectroscopy. Journal of Physical Chemistry B 116 (1), pp. 314-323.

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Abstract

Dielec. relaxation (DR) spectra have been measured for aq. solns. of sodium formate (NaOFm) and sodium acetate (NaOAc) over a wide range of frequencies (0.2 ≤ ν/GHz ≤ 89) up to solute concns. c .ltorsim. 3.2 M and .ltorsim. 3.7 M, resp., at 25°. Measurements were also made on NaOAc(aq) at 15 ≤ T/°C ≤ 35. In addn. to the usual dominant bulk-water relaxation process at ∼20 GHz, one or two further ...

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Item Type:Article
Date:2012
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1021/jp207504dDOI
CODEN:JPCBFKOther
Keywords:hydration sodium formate acetate aq soln dielec relaxation
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:15 May 2012 12:22
Last Modified:15 May 2012 12:22
Item ID:24355
Owner Only: item control page
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