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Hydration of Formate and Acetate Ions by Dielectric Relaxation Spectroscopy

Rahman, H.M.A. and Hefter, Glenn and Buchner, Richard (2012) Hydration of Formate and Acetate Ions by Dielectric Relaxation Spectroscopy. Journal of Physical Chemistry B 116 (1), pp. 314-323.

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Dielec. relaxation (DR) spectra have been measured for aq. solns. of sodium formate (NaOFm) and sodium acetate (NaOAc) over a wide range of frequencies (0.2 ≤ ν/GHz ≤ 89) up to solute concns. c .ltorsim. 3.2 M and .ltorsim. 3.7 M, resp., at 25°. Measurements were also made on NaOAc(aq) at 15 ≤ T/°C ≤ 35. In addn. to the usual dominant bulk-water relaxation process at ∼20 GHz, one or two further ...


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Item Type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
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Keywords:hydration sodium formate acetate aq soln dielec relaxation
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited On:15 May 2012 12:22
Last Modified:15 May 2012 12:22
Item ID:24355
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