Nasirzadeh, Karamat and Papaiconomou, Nicolas and Neueder, Roland and Kunz, Werner (2004) Vapor pressures, osmotic and activity coefficients of electrolytes in protic solvents at different temperatures. Part 1. Lithium bromide in methanol. Journal of Solution Chemistry 33 (3), pp. 227-245.
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Precise vapor pressure data for LiBr solns. in MeOH are given for temps. ranging from 298.15-333.15 K. The molality range is from 0.0411-6.8675 mol-kg-1. Osmotic coeffs. were calcd. by taking into account the 2nd virial coeff. of MeOH. The parameters of the Pitzer-Mayorga model, the Archer extension of the Pitzer-Mayorga model, the mole-fraction-based thermodn. model of Clegg-Pitzer, and the recently developed MSA-NRTL model are evaluated, along with the corresponding std. deviation. These equations were used to calc. activity coeffs. of LiBr in MeOH solns.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz|
|Keywords:||lithium bromide methanol vapor pressure osmotic activity coeff|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||25 May 2012 08:38|
|Last Modified:||25 May 2012 08:38|