Kunz, Werner and Calmettes, P. and Jannink, G. and Belloni, L. and Cartailler, T. and Turq, P. (1992) The charge structure factor of a 1-1 electrolyte in solution. Journal of Chemical Physics 96 (9), pp. 7034-7028.
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The charge structure factor of a 1-1 electrolyte soln. was measured by means of small angle neutron scattering. To this end the system was chosen so as to achieve a zero av. contrast for the salt. The data are used to test the Stillinger and Lovett sum rules, and also to test the modelization of the soln. structure including short range as well as Coulombic interactions. This modelization is based on the hypernetted chain integral equation and on suitable solvent-averaged pair potentials. At small values of wave no. transfer, the exptl. results are compared to a new approxn. for the charge structure factor.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz|
|Keywords:||charge structure factor triethylphenylammonium tetraphenylborate DMF|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||31 May 2012 08:30|
|Last Modified:||31 May 2012 08:30|