Deutsch
Sangoro, Joshua and Iacob, Ciprian and Naumov, S. and Valiullin, R. and Rexhausen, H. and Hunger, J. and Buchner, Richard and Strehmel, V. and Kärger, J. and Kremer, Friedrich (2011) Diffusion in ionic liquids: the interplay between molecular structure and dynamics. Soft Matter 7 (5), pp. 1678-1681.
Full text not available from this repository.
Abstract
Diffusion in a series of ionic liqs. is investigated by a combination of Broadband Dielec. Spectroscopy (BDS) and Pulsed Field Gradient NMR (PFG NMR). It is demonstrated that the mean jump lengths increase with the mol. vols. detd. from quantum-chem. calcns. This provides a direct means-via Einstein-Smoluchowski relation-to det. the diffusion coeff. by BDS over more than 8 decades unambiguously and in quant. agreement with PFG NMR measurements. New possibilities in the study of charge transport and dynamic glass transition in ionic liqs. are thus opened.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner | ||||
| Identification Number: |
| ||||
| Keywords: | ionic liq diffusion mol structure dynamics | ||||
| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Georg Berger | ||||
| Deposited On: | 06 Jun 2012 15:55 | ||||
| Last Modified: | 06 Jun 2012 15:55 | ||||
| Item ID: | 24713 |
- ASCII Citation
- BibTeX
- Dublin Core
- EndNote
- HTML Citation
- METS
- OAI-ORE Resource Map (Atom Format)
- OAI-ORE Resource Map (RDF Format)
- RDF+N-Triples
- RDF+N3
- RDF+XML
- Refer
- Reference Manager
- Simple Metadata
- XML
- xMetaDissPlus
Literature of the same author
in this repositoryat BASEat Google Scholarat Scirusat publisher (via DOI)
Bookmark
Citeulike
Connotea
Del.icio.us
Digg
Facebook