Bester-Rogac, M. and Hunger, J. and Stoppa, A. and Buchner, Richard (2010) Molar Conductivities and Association Constants of 1-Butyl-3-methylimidazolium Chloride and 1-Butyl-3-methylimidazolium Tetrafluoroborate in Methanol and DMSO. Journal of Chemical & Engineering Data 55 (5), pp. 1799-1803.
Full text not available from this repository.
Molar conductivities, Λ, of dil. solns. of the ionic liqs. 1-butyl-3-methylimidazolium chloride and 1-butyl-3-methylimidazolium tetrafluoroborate in methanol and DMSO were detd. as a function of temp. (methanol, T = (273.15 to 313.15) K; DMSO, T = (293.15 to 318.15) K). The data were analyzed with Barthel's low-concn. chem. model (lcCM) model to obtain the limiting molar conductivities, Λ∞(T), and assocn. consts., K°A(T), of these electrolytes. From Λ∞(T), the Eyring activation enthalpy of charge transport and (where possible) the ion cond. of the cation, λ∞([bmim]+), were detd.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner|
|Keywords:||molar cond assocn const butylmethylimidazolium chloride fluoroborate methanol DMSO|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||08 Jun 2012 10:47|
|Last Modified:||08 Jun 2012 10:47|