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Scandium Sulfate Complexation in Aqueous Solution by Dielectric Relaxation Spectroscopy

Schrödle, S. and Wachter, Wolfgang and Buchner, Richard and Hefter, Glenn (2008) Scandium Sulfate Complexation in Aqueous Solution by Dielectric Relaxation Spectroscopy. Inorganic Chemistry 47 (19), pp. 8619-8628.

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Abstract

Ion assocn. in aq. solns. of scandium sulfate has been investigated at 25 °C and at concns. from 0.01 to 0.8 M by broadband dielec. spectroscopy over the frequency range 0.2 ≤ ν/GHz ≤ 89. Detailed anal. of the spectra reveals the presence of both inner- and outer-sphere 1:1 [ScSO4]+(aq) complexes, similar to solns. of other high-valent metal sulfates. Outer-outer-sphere 1:1 complexes are ...

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Item Type:Article
Date:2008
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1021/ic702396rDOI
Keywords:scandium cation sulfate complexation aq soln dielec relaxation spectroscopy
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:08 Jun 2012 10:42
Last Modified:08 Jun 2012 10:42
Item ID:24769
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