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Glasslike behavior in aqueous electrolyte solutions

Turton, D.A. and Hunger, J. and Hefter, Glenn and Buchner, Richard and Wynne, K. (2008) Glasslike behavior in aqueous electrolyte solutions. Journal of Chemical Physics 128 (16), 161102/1-161102/4.

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When salts are added to water, generally the viscosity increases, suggesting that the ions increase the strength of the water's hydrogen-bond network. However, IR pump-probe measurements on electrolyte solns. have found that ions have no influence on the rotational dynamics of water mols., implying no enhancement or breakdown of the hydrogen-bond network. Here, the authors report optical Kerr ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
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Keywords:electrolyte aq soln electrooptical Kerr effect dielec loss
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited on:11 Jun 2012 05:43
Last modified:11 Jun 2012 05:43
Item ID:24775
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