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Dielectric relaxation of aqueous NaF and KF solutions

Buchner, Richard and Hefter, Glenn and Barthel, Josef (1994) Dielectric relaxation of aqueous NaF and KF solutions. Journal of the Chemical Society, Faraday Transactions 90 (17), pp. 2475-2479.

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Dielec. relaxation expts. in the frequency range 0.45 ≤ ν/GHz ≤ 89 are presented for aq. solns. of NaF and KF at 25°. The complex permittivity spectra reveal two dispersion steps attributed to the cooperative reaction of the solvent, τs ≈ 8 ps, and to the formation of a small quantity of predominantly solvent-sepd. ion pairs, τIP ≈ 100 ps. The dielec. decrement obsd. for the solvent ...


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Item Type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
Keywords:dielec relaxation aq sodium potassium fluoride solvation aq sodium potassium fluoride ion pair aq sodium potassium fluoride
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited On:14 Jun 2012 06:00
Last Modified:14 Jun 2012 06:00
Item ID:24877
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