Contact Imprint

A Facile Strategy to a New Fluorous-Tagged, Immobilized TEMPO Catalyst Using a Click Reaction, and Its Catalytic Activity

Gheorghe, Alexandru and Cuevas-Yañez, Erick and Horn, Joachim and Bannwarth, Willi and Narsaiah, Banda and Reiser, Oliver (2006) A Facile Strategy to a New Fluorous-Tagged, Immobilized TEMPO Catalyst Using a Click Reaction, and Its Catalytic Activity. Synlett 2006 (17), pp. 2767-2770.

[img]
PDF - Repository staff only - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
93Kb

Other URL: http://dx.doi.org/10.1055/s-2006-950256

Abstract

A new fluorous-tagged TEMPO catalyst was prepared
by a facile approach using the copper-catalyzed azide-alkyne cycloaddition as the ligation method. A fluorous F17-CLICK-TEMPO showed excellent activity and selectivity in the oxidation of alcohols to aldehydes using bleach as the terminal oxidant. Moreover, the catalyst could be easily recovered using silica gel 60 and recycled in four cycles without loss of activity.

Item Type:Article
Institutions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1055/s-2006-950256DOI
Keywords:catalyst immobilization; fluorous; oxidation; click chemistry; TEMPO
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner:Ute Lange
Deposited On:18 Oct 2007
Last Modified:20 Jul 2011 23:11
Item ID:2530
Export bibliographical data
Literature of the same author
plusin this repository
plusat BASE
plusat Google Scholar
plusat Scirus
at publisher (via DOI)
Bookmark
Owner Only: item control page
University Library of Regensburg - 93042 Regensburg, Germany - University
Tel.: 0941 943-3990 (Information) - Contact Information - Imprint

The Publicationserver supports supports OAI 2.0 with a base URL of http://epub.uni-regensburg.de/cgi/oai2