Gheorghe, Alexandru and Cuevas-Yañez, Erick and Horn, Joachim and Bannwarth, Willi and Narsaiah, Banda and Reiser, Oliver (2006) A Facile Strategy to a New Fluorous-Tagged, Immobilized TEMPO Catalyst Using a Click Reaction, and Its Catalytic Activity. Synlett 2006 (17), pp. 2767-2770.
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Other URL: http://dx.doi.org/10.1055/s-2006-950256
A new fluorous-tagged TEMPO catalyst was prepared
by a facile approach using the copper-catalyzed azide-alkyne cycloaddition as the ligation method. A fluorous F17-CLICK-TEMPO showed excellent activity and selectivity in the oxidation of alcohols to aldehydes using bleach as the terminal oxidant. Moreover, the catalyst could be easily recovered using silica gel 60 and recycled in four cycles without loss of activity.
|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser|
|Keywords:||catalyst immobilization; fluorous; oxidation; click chemistry; TEMPO|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||18 Oct 2007|
|Last Modified:||20 Jul 2011 21:11|