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First Determination of the Rate Acceleration of a Palladium Catalyzed Coupling Reaction by High Pressure

Hillers, Stephan and Reiser, Oliver (1996) First Determination of the Rate Acceleration of a Palladium Catalyzed Coupling Reaction by High Pressure. Chemical Communications: ChemComm 1996 (18), pp. 2197-2198.

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Other URL: http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=CC9960002197


Abstract

The activation volume, ΔV‡, reflecting the rate acceleration by pressure, of the coupling reaction between 2,3-dihydrofuran and iodobenzene is determined as –12 ± 2 cm⁻³ by kinetic measurements at pressures between 1 bar and 8 kbar; moreover, our kinetic data suggest that the rate-determining step is not the oxidative addition of iodobenzene to the palladium ...

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Item Type:Article
Date:1996
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1039/CC9960002197DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Helge Knüttel (ADMIN)
Deposited On:22 Aug 2006
Last Modified:05 Aug 2009 13:22
Item ID:286
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