Hillers, Stephan and Reiser, Oliver (1996) First Determination of the Rate Acceleration of a Palladium Catalyzed Coupling Reaction by High Pressure. Chemical Communications: ChemComm 1996 (18), pp. 2197-2198.
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The activation volume, ΔV‡, reflecting the rate acceleration by pressure, of the coupling reaction between 2,3-dihydrofuran and iodobenzene is determined as –12 ± 2 cm⁻³ by kinetic measurements at pressures between 1 bar and 8 kbar; moreover, our kinetic data suggest that the rate-determining step is not the oxidative addition of iodobenzene to the palladium catalyst.
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|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser|
|Dewey Decimal Classification:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Unknown|
|Deposited on:||22 Aug 2006|
|Last modified:||05 Aug 2009 13:22|