Startseite UB

High-Pressure Induced Domino-Horner-Wadsworth-Emmons (HWE) -Michael Reactions

Has-Becker, Senay and Bodmann, Kerstin and Kreuder, Reinhard and Santoni, Gabriella and Rein, Tobias and Reiser, Oliver (2001) High-Pressure Induced Domino-Horner-Wadsworth-Emmons (HWE) -Michael Reactions. Synlett 2001 (9), pp. 1395-1398.

Full text not available from this repository.

at publisher (via DOI)

Other URL: http://www.thieme-connect.com/ejournals/abstract/synlett/doi/10.1055/s-2001-16786


Abstract

A new protocol for the alkenylation of carbonyl compounds with phosphonates (Horner-Wadsworth-Emmons reaction) is described. Aldehydes react with phosphonates already at room temperature in the presence of triethylamine without further activation by Lewis-acids if high-pressure (8 kbar) is applied to the system. Based on this protocol a domino process was developed combining the HWE reaction with ...

plus


Export bibliographical data



Item Type:Article
Date:2001
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1055/s-2001-16786DOI
Keywords:Horner-Wadsworth-Emmons reaction; Michael addition; domino reaction; β-amino esters; β-thio esters; β-thio nitriles; high-pressure
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Helge Knüttel (ADMIN)
Deposited On:01 Sep 2006
Last Modified:05 Aug 2009 13:22
Item ID:323
Owner Only: item control page
  1. University

University Library

Publication Server

Contact person
Gernot Deinzer

Telefon 0941 943-2759
Contact