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Cobalt(II)-Azabis(oxazoline)-Catalyzed Conjugate Reduction of α,β-Unsaturated Carbonyl Compounds.

Geiger, Christian and Kreitmeier, Peter and Reiser, Oliver (2005) Cobalt(II)-Azabis(oxazoline)-Catalyzed Conjugate Reduction of α,β-Unsaturated Carbonyl Compounds. Advanced Synthesis & Catalysis 347 (2-3), pp. 249-254.

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Other URL: http://dx.doi.org/10.1002/adsc.200404295


Azabis(oxazolines) prove to be superior ligands for the enantioselective, cobalt(II)-catalyzed conjugate reduction of α,β-unsaturated carbonyl compounds with sodium borohydride. β-Trisubstituted α,β-unsaturated esters and amides as well as γ-butenolides are readily converted to their corresponding saturated counterparts with enantioselectivities up to 97% ee.

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Item type:Article
Date:14 February 2005
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
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Keywords:azabis(oxazolines); cobalt; conjugate reduction; transition metals; α,β-unsaturated amides; α,β-unsaturated esters
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Deposited on:05 Sep 2006
Last modified:05 Aug 2009 13:22
Item ID:343
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