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The role of binding constant in the efficiency of chiral catalysts immobilized by electrostatic interactions. The case of azabis(oxazoline)-copper complexes

Fraile, José M. and García, José I. and Herrerías, Clara I. and Mayoral, José A. and Reiser, Oliver and Socuéllamos, Antonio and Werner, Heiko (2004) The role of binding constant in the efficiency of chiral catalysts immobilized by electrostatic interactions. The case of azabis(oxazoline)-copper complexes. Chemistry - A European Journal 10 (12), pp. 2997-3005.

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Other URL: http://dx.doi.org/10.1002/chem.200305739


Abstract

As shown by theoretical calculations, azabis(oxazoline)-copper complexes are considerably more stable than the analogous bis(oxazoline)-copper complexes. This enhanced stability allows them to be efficiently immobilized by means of electrostatic interactions to different anionic supports, such as clays and nafion-silica nanocomposites, without the loss of a ligand, as is observed for ...

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Item Type:Article
Date:21 June 2004
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1002/chem.200305739DOI
Keywords:cyclopropanation; enantioselectivity; heterogeneous catalysts; immobilized catalysts; N ligands
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Helge Knüttel (ADMIN)
Deposited On:04 Sep 2006
Last Modified:05 Aug 2009 13:22
Item ID:349
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