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Enantiomerically pure pentagonal-bipyramidal metal complexes with predetermined helicity in the solid and the solution state

Seitz, Michael and Kaiser, Anja and Stempfhuber, Sabine and Zabel, Manfred and Reiser, Oliver (2005) Enantiomerically pure pentagonal-bipyramidal metal complexes with predetermined helicity in the solid and the solution state. Inorganic Chemistry 44 (13), pp. 4630-4636.

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Other URL: http://dx.doi.org/10.1021/ic050014b


Abstract

New metal complexes with pentagonal-bipyramidal geometry have been synthesized with the chiral, pentadentate bis(oxazoline) ligand (R,R)-1, including the metal ions magnesium(II), iron(II), and cadmium(II). In the solid state, a complete transfer of chirality from the ligand is observed to exclusively yield enantiomerically pure P-helical, isostructural pentagonal bipyramidal complexes, as ...

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Item Type:Article
Date:27 June 2005
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1021/ic050014bDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Helge Knüttel (ADMIN)
Deposited On:05 Sep 2006
Last Modified:05 Aug 2009 13:22
Item ID:358
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