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Electrochemical oxidation of 2-substituted piperidines as a key step towards the synthesis of hydroxylated γ-amino acids

Bodmann, Kerstin and Bug, Thorsten and Steinbeisser, Sabine and Kreuder, Reinhard and Reiser, Oliver (2006) Electrochemical oxidation of 2-substituted piperidines as a key step towards the synthesis of hydroxylated γ-amino acids. Tetrahedron Letters 47 (13), pp. 2061-2064.

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Other URL: http://dx.doi.org/10.1016/j.tetlet.2006.01.141


Abstract

2-Substituted piperidines containing different oxygenated side chain functionalities were investigated in the electrochemical, anodic methoxylation. Surprisingly, the configuration of the side chain has a strong influence on the outcome of the electrochemical oxidation. Subsequent elimination of methanol from the oxidation products leads to N-protected eneamides, which upon ozonolysis can be ...

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Item Type:Article
Date:27 March 2006
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1016/j.tetlet.2006.01.141DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Helge Knüttel (ADMIN)
Deposited On:06 Sep 2006
Last Modified:05 Aug 2009 13:22
Item ID:369
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