Dick, Bernhard and Hochstrasser, R. M. (1983) Spectroscopy using sum- and difference-frequency generation in molecular solids. Physical Review Letters 51 (24), pp. 2221-2223.
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Abstract
Both sum- and difference-frequency generation in org. materials were demonstrated and explored under conditions where all 3 waves (w1 and w2 ingoing and w1 +- w2 out-going) were resonant with mol. transitions. The expts. were carried out in centrosym. media in which a small elec. field was used to distinguish the polar sublattices. Unique elec. field dependences of the paramagnetic signals were discovered. The spectroscopic line narrowing and dephasing-induced coherent-emission resonances of these c(2) processes make them useful new spectroscopic methods.
| Item Type: | Article | ||||||
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| Additional information (public): | CAN 100:27690 73-4 Optical, Electron, and Mass Spectroscopy and Other Related Properties 91-20-3 Role: PRP (Properties) (luminescence of azulene in matrix of, sum- and difference-frequencies in); 275-51-4 Role: PRP (Properties) (luminescence of, in naphthalene matrix, sum- and difference frequencies in) | ||||||
| Institutions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Bernhard Dick | ||||||
| Identification Number: |
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| Keywords: | Laser radiation (luminescence induced by, of azulene and naphthalene matrix, sum- and difference-frequencies in); Luminescence (of azulene in naphthalene matrix, sum- and difference-frequencies in); Spectrometry (of mol. solids using sum- and difference-frequency generation with Stark effect switching); Stark effect (switching in spectroscopy of mol. solids using sum- and difference-frequency generation); electronic spectroscopy laser mol solid; azulene solid matrix luminescence | ||||||
| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||||
| Status: | Published | ||||||
| Refereed: | Yes, this version has been refereed | ||||||
| Created at the University of Regensburg: | No | ||||||
| Owner: | Universitätsbibliothek Regensburg | ||||||
| Deposited On: | 22 Jan 2009 11:16 | ||||||
| Last Modified: | 17 Jan 2012 15:49 | ||||||
| Item ID: | 5513 |
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