Startseite UB

Dependence of enantioselectivity on the ligand/metal ratio in the asymmetric Michael addition of indole to benzylidene malonates: Electronic influence of substrates

Schatz, A. and Rasappan, R. and Hager, M. and Gissibl, A. and Reiser, O. (2008) Dependence of enantioselectivity on the ligand/metal ratio in the asymmetric Michael addition of indole to benzylidene malonates: Electronic influence of substrates. Chemistry - A European Journal 14 (24), pp. 7259-7265.

Full text not available from this repository.

at Web of Science

at publisher (via DOI)


Abstract

Simple bis(oxazoline) ligands, especially azabis(oxazolines), call promote the copper(II)-catalyzed Michael addition of indoles to benzylidene malonates with up to > 99% ee (ee = enantiomeric excess), provided that the ligand/metal ratio is tuned meticulously With particular regard to the electronic properties of the Substrate. Despite a common paradigm followed in many asymmetric catalyses, an ...

plus


Export bibliographical data

Item Type:Article
Date:2008
Additional information (public):Schätz, Alexander; Rasappan, Ramesh; Hager, Markus; Gissibl, Anja; Reiser, Oliver
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
ISI:000258801500019Web of Science ID
10.1002/chem.200800508DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Oliver Reiser
Deposited On:09 Feb 2009 10:04
Last Modified:16 Nov 2009 14:09
Item ID:5720
Owner Only: item control page
  1. University

University Library

Publication Server

Contact person
Gernot Deinzer

Telefon 0941 943-2759
Contact