König, B. and Pitsch, W. and Klein, M. and Vasold, R. and Prall, M. and Schreiner, P. R. (2001) Carbonyl- and Carboxyl-substituted Enediynes: Synthesis, Computations, and Thermal Reactivity. J. Org. Chem. 66, pp. 1742-1746.
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The influence of electron-withdrawing groups (carbonyl and carboxyl) at the alkyne termini on the reactivity of enediynes was investigated by a combination of experimental and computational techniques. While the general chemical reactivity of such enediynes, especially if non-benzannelated, is increased markedly, the thermal cyclization, giving rise to Bergman cyclization products, is changed ...
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|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König|
|Projects:||GRK 760, Graduiertenkolleg Medizinische Chemie|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||05 Mar 2009 10:53|
|Last Modified:||09 Nov 2010 16:00|