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NADH Model Systems functionalized with Zn(II)-cyclen as Flavin Binding Site  Structure Dependence of the Redox Reaction within reversible Aggregates

Reichenbach-Klinke, R. and Kruppa, M. and König, B. (2002) NADH Model Systems functionalized with Zn(II)-cyclen as Flavin Binding Site  Structure Dependence of the Redox Reaction within reversible Aggregates. J. Am. Chem. Soc. 124, 12999 - 13007.

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Abstract

The relative positions and conformations of the prosthetic group FAD and the cofactor NADH have been remarkably conserved within the structurally diverse group of flavin enzymes. To provide a chemical rational for such an obviously optimal relative disposition of the redox partners for efficient reaction we have synthesized NADH models with Zn(II)-cyclen substituents for reversible flavin binding ...

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Item Type:Article
Date:2002
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identification Number:
ValueType
10.1021/ja026719jDOI
12405826PubMed ID
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:54
Last Modified:15 Jul 2011 08:44
Item ID:6226
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