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Catalytic Photooxidation of 4-Methoxybenzyl alcohol with a Flavin Zinc(II) cyclen complex

Cibulka, R. and Vasold, R. and König, B. (2004) Catalytic Photooxidation of 4-Methoxybenzyl alcohol with a Flavin Zinc(II) cyclen complex. Chem. Eur. J. 10, 6223 – 6231.

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Abstract

Flavin-zinc(II)-cyclen 10 contains a covalently linked substrate binding site (zinc(II)-cyclen) and a chromophore unit (flavin). Upon irradiation, compound 10 effectively oxidizes 4-methoxybenzyl alcohol (11-OCH3) to the corresponding benzaldehyde both in water and in acetonitrile. In the presence of air, the reduced flavin 10-H2 is reoxidized, and so catalytic amounts of 10 are sufficient for ...

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Item Type:Article
Date:2004
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identification Number:
ValueType
10.1002/chem.200400232DOI
15487030 PubMed ID
Keywords:electron transfer · flavin · macrocyclic ligands · photooxidation · sensitizers
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:54
Last Modified:11 Mar 2011 08:55
Item ID:6245
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