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A Luminescent Receptor with Affinity for N-terminal Histidine in Peptides in Aqueous Solution

Kruppa, M. and Mandl, C. and Miltschitzky, S. and König, B. (2005) A Luminescent Receptor with Affinity for N-terminal Histidine in Peptides in Aqueous Solution. J. Am. Chem. Soc. 127, 3362 - 3365.

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Abstract

Crown ethers of suitable size are the perfect artificial host compounds for ammonium ion binding, but the rather low affinity in aqueous solution prevents their use at physiological conditions. We report here the synthesis and properties of a luminescent benzo crown ether with a pendant copper imidodiacetic acid complex, which coordinates with high affinity to histidine. The emission intensity of ...

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Item Type:Article
Date:2005
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 760, Graduiertenkolleg Medizinische Chemie
Identification Number:
ValueType
10.1021/ja043930hDOI
15755153PubMed ID
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:54
Last Modified:09 Nov 2010 10:47
Item ID:6253
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