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Photooxidation of Benzyl Alcohols with Immobilized Flavins

Schmaderer, Harald and Hilgers, Petra and Lechner, Robert and König, Burkhard (2009) Photooxidation of Benzyl Alcohols with Immobilized Flavins. Advanced Synthesis & Catalysis 351, pp. 163-174.

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Abstract

Benzyl alcohols are oxidized cleanly and efficiently to the corresponding aldehydes under irradiation using flavin photocatalysts and aerial oxygen as the terminal oxidant in homogeneous aqueous solution. Turnover frequencies (TOF) of more than 800 h⁻¹ and turnover numbers (TON) of up to 68 were obtained. Several flavin photocatalysts with fluorinated or hydrophobic aliphatic chains were ...

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Item Type:Article
Date:2009
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 640 Sensory photoreceptors in natural and artificial systems
Identification Number:
ValueType
10.1002/adsc.200800576DOI
Keywords:catalyst recycling; flavins; fluorous chemistry; immobilization; photooxidation; redox chemistry
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Regina Hoheisel
Deposited On:05 Jun 2009 14:31
Last Modified:27 Aug 2012 13:02
Item ID:7276
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