Schmaderer, Harald and Hilgers, Petra and Lechner, Robert and König, Burkhard (2009) Photooxidation of Benzyl Alcohols with Immobilized Flavins. Advanced Synthesis & Catalysis 351, pp. 163-174.
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Benzyl alcohols are oxidized cleanly and efficiently to the corresponding aldehydes under irradiation using flavin photocatalysts and aerial oxygen as the terminal oxidant in homogeneous aqueous solution. Turnover frequencies (TOF) of more than 800 h⁻¹ and turnover numbers (TON) of up to 68 were obtained. Several flavin photocatalysts with fluorinated or hydrophobic aliphatic chains were ...
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|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König|
|Projects:||GRK 640 Sensory photoreceptors in natural and artificial systems|
|Keywords:||catalyst recycling; flavins; fluorous chemistry; immobilization; photooxidation; redox chemistry|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||05 Jun 2009 14:31|
|Last Modified:||27 Aug 2012 13:02|