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Luminescent Metal-Ligand Complexes as Labels for Polarization Immunoassays and for Determination of Hydrogen Peroxide

URN to cite this document: urn:nbn:de:bvb:355-opus-881

Dürkop, Axel (2002) Luminescent Metal-Ligand Complexes as Labels for Polarization Immunoassays and for Determination of Hydrogen Peroxide. PhD, Universität Regensburg

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Abstract (German)

Es wurden zwei Ruthenium Metall-Liganden Komplexe synthetisiert, die entweder 5-carboxy-2,2�-bipyridin oder 5,5�-dicarboxy-2,2�-bipyridin als asymmetrischen Liganden enthalten. Die Absorptionsmaxima sind um 450 nm und die Emissionsmaxima sind bei 675 nm und 705 nm. Die Emissionsmaxima werden bis zu 30 nm rotverschoben, wenn der Komplex kovalent an ein Protein gebunden ist. Die ...

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Translation of the abstract (English)

Two metal-ligand complexes were synthesized containing 5-carboxy-2,2� -bipyridine and 5,5�-dicarboxy-2,2�-bipyridine as the asymmetric ligand. The absorption maxima were found to be around 450 nm and the emission maxima are 675 nm and 705 nm, respectively. The fundamental polarization values were 0.33 for [Ru(2,2�-bipyridine)2(5,5�-dicarboxy-2,2�-bipyridine)](PF6)2 and 0.18 for ...

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Item Type:Thesis of the University of Regensburg (PhD)
Date:9 July 2002
Referee:Prof. Dr. Otto S. Wolfbeis
Date of exam:27 April 2001
Institutions:Chemistry and Pharmacy > Institut für Analytische Chemie, Chemo- und Biosensorik > Chemo- und Biosensorik (Prof. Otto S. Wolfbeis)
Keywords:Immunoassay , Fluoreszenzpolarisation , Rutheniumkomplexe , Europium , Wasserstoffperoxid , , Polarizationimmunoassay , Metal-Ligand Complex , Ruthenium , Europium , Hydrogen Peroxide
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:21 Oct 2009 13:41
Last Modified:13 Mar 2014 11:09
Item ID:9932
Owner Only: item control page

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