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Supramolekulare Chemie mit Ammoniak - Strukturchemie neuer Ammoniak-Proton-Komplexe

URN to cite this document:
urn:nbn:de:bvb:355-opus-5410
DOI to cite this document:
10.5283/epub.10334
Roßmeier, Thomas
Date of publication of this fulltext: 23 Aug 2005 07:00


Abstract (German)

Zusammenfassung Folgende isolierte Ammoniak-Proton-Komplexkationen können nachgewiesen werden: [NH4(NH3)2]+, [NH4(NH3)3]+, [NH4(NH3)4]+, [{NH4(NH3)4}2(mu-NH3)2]2+, [NH4(NH3)9]+, und [(NH4)2(NH3)3]2+. Hinzu kommen noch ausgedehnte Ammoniak-Proton-Komplexkationen: [{N26H80}2+(mu-NH3)2], [NH4(NH3)4+(mu-NH3)2] und [(NH4+)4(NH3)42]. Das ausgedehnte [(NH4+)4(NH3)42]-Komplexkation ist in der ...

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Translation of the abstract (English)

Summary The following isolated ammonia proton complex cations can be proven: [NH4(NH3)2]+, [NH4(NH3)3]+, [NH4(NH3)4]+, [{NH4(NH3)4}2(mu-NH3)2]2+, [NH4(NH3)9]+, and [(NH4)2(NH3)3]2+. The extended ammonia proton complex cations can also be documented: [{N26H80}2+(mu-NH3)2], [NH4(NH3)4+(mu-NH3)2] and [(NH4+)4(NH3)42]. The extended [(NH4+)4(NH3)42]-complex cation is in the structure of ...

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