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Investigations into tin- and tantalum-phosphorus compounds for low-coordinate moieties and supramolecular assemblies

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Johnson, Brian P.
Date of publication of this fulltext: 23 Jan 2006 07:42

Abstract (English)

In this work, metal-phosphorus chemistry was approached in the following four aspects: i) the stabilization of new tin-phosphorus ligands in the coordination sphere of transition-metal fragments; ii) the kinetic stabilization of low-coordinate tin-phosphorus compounds with a bulky terphenyl ligand; iii) the preparation of a new tris(aryloxy)amine-tantalum complex and the study of its potential ...


Translation of the abstract (German)

In dieser Arbeit wurde die Metall-Phosphor-Chemie in den folgenden vier Aspekten behandelt: i) die Stabilisierung neuer Zinn-Phosphor-Liganden mit Übergangsmetallfragmenten; ii) die kinetische Stabilisierung von niedrigkoordinierten Zinn-Phosphor-Verbindungen mit einem sterisch anspruchsvollen Terphenyl-Liganden; iii) die Darstellung eines neuen Tris(aryloxy)amintantal-Komplexes; und iv)die ...


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