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Organometallic P-ligand complexes as supramolecular building blocks

URN to cite this document:
urn:nbn:de:bvb:355-opus-6598
Gregoriades, Laurence John
Date of publication of this fulltext: 08 Feb 2007 08:09


Abstract (English)

The propensity of P-ligand complexes to act as linking units for various transition metal centres has been investigated and a number of novel supramolecular aggregates have been isolated and comprehensively characterised. Some of these assemblies exhibit dynamic behaviour in solution and a tendency to undergo extensive dissociation, as demonstrated by solution NMR and vapour pressure osmometry ...

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Translation of the abstract (German)

Die Neigung von P-Ligandkomplexen, als verbindende Einheiten für verschiedene Übergangsmetallzentren zu fungieren, wurde untersucht. Ebenso wurde eine Anzahl von neuartigen supramolekularen Aggregaten isoliert und umfassend charakterisiert. Einige dieser Aggregate zeigen dynamisches Verhalten und extensive Dissoziation in Lösung, was anhand der Daten von NMR-Untersuchungen und ...

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