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Organocuprate Conjugate Addition: The Structural Features of Diastereomeric and Supramolecular p-Intermediates

Henze, W., Gärtner, T. and Gschwind, R. M. (2008) Organocuprate Conjugate Addition: The Structural Features of Diastereomeric and Supramolecular p-Intermediates. Journal of the American Chemical Society 130 (41), pp. 13718-13726.

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Abstract

In the reaction pathway of conjugate additions with organocuprate reagents, Cu(I) π-complexes and Cu(III) σ-complexes have been identified as central, NMR-detectable intermediate species. However, no experimental evidence for the structures of π-intermediates with extensive chiral enones or the principal aggregation level and aggregate structure of π-complexes in diethyl ether has been available ...

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Item type:Article
Date:2008
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1021/ja8041433DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:10621
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