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The H-Bonding Network of Acylguanidine Complexes: Combined Intermolecular 2hJH,P and 3hJN,P Scalar Couplings Provide an Insight into the Geometric Arrangement

Federwisch, G. ; Kleinmaier, R. ; Drettwan, D. ; Gschwind, R. M.



Abstract

The H-bonding networks of arginines and acylguanidines are crucial for many biological and pharmaceutical interactions. However, the effect of acylation of guanidines on the binding mode and the H-bond strengths has not yet been explored in solution. Therefore, the H-bonding network of a 15N labeled acylguanidine derivative in a bisphosphonate arginine receptor is investigated. The direct NMR ...

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