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A eta2-triflate (OTf) intermediate in the solution dynamics of PtMe3(OTf)*TMEDA: the windscreen-wiper process revisited

Gschwind, R. M. and Schlecht, S. (1999) A eta2-triflate (OTf) intermediate in the solution dynamics of PtMe3(OTf)*TMEDA: the windscreen-wiper process revisited. Dalton Transactions (11), pp. 1891-1895.

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Abstract

The reaction of tetrameric [PtMe3(OTf)]4 (OTf = triflate = CF3SO3–) with TMEDA (N,N,N,N-tetramethylethylenediamine) gave the monomeric compound PtMe3(OTf)·TMEDA in quantitative yield. The non-planar TMEDA ligand contains two different sorts of methyl groups in PtMe3(OTf)·TMEDA, and thus offers a second and independent set of NMR parameters in addition to the commonly used signals of the Me3Pt ...

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Item type:Article
Date:1999
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1039/a809811eDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:No
Item ID:10655
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