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A eta2-triflate (OTf) intermediate in the solution dynamics of PtMe3(OTf)*TMEDA: the windscreen-wiper process revisited

Gschwind, R. M. ; Schlecht, S.



Abstract

The reaction of tetrameric [PtMe3(OTf)]4 (OTf = triflate = CF3SO3–) with TMEDA (N,N,N,N-tetramethylethylenediamine) gave the monomeric compound PtMe3(OTf)·TMEDA in quantitative yield. The non-planar TMEDA ligand contains two different sorts of methyl groups in PtMe3(OTf)·TMEDA, and thus offers a second and independent set of NMR parameters in addition to the commonly used signals of the Me3Pt ...

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