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Synthesis of supramolecular architectures using Pn-ligands as building blocks

URN to cite this document:
urn:nbn:de:bvb:355-opus-8095
Deng, Shining
Date of publication of this fulltext: 11 Jul 2008 16:13


Abstract (English)

In this thesis, chemical properties and coordination behaviors of different Pn-ligand complexes were studied and following aspects are engaged: i) The lone pairs of electrons on the phosphorus atoms in the Pn-ligands give a ligation propensity to transition metal centers, which lead to oligomers or polymers; ii) The ligation mode of P5-nCn-ring (n = 0-2) ligands toward the transition metal ...

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Translation of the abstract (German)

In dieser Doktorarbeit wurden die chemischen Eigenschaften und das Koordinationsverhalten von verschiedenen Pn-Ligand-Komplexen untersucht. Folgende Aspekte wurden festgestellt: i) Das freie Elektronenpaar der Phosphoratome in Pn-Liganden besitzt die Neigung Übergangsmetallzentren zu koordinieren und damit Oligomer- bzw. Polymerspezies zu bilden; ii) Der Koordinationsmodus von P5-nCn-Ring (n = ...

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