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Monomere Verbindungen der Elemente der 13. und 15. Gruppe

URN to cite this document:
urn:nbn:de:bvb:355-opus-9088
Adolf, Ariane
Date of publication of this fulltext: 12 Dec 2008 16:21


Abstract (German)

Alle Versuche die wasserstoffsubstituierte Stammverbindung der Phosphanylborane A (A: H2P�BH2) zu synthetisieren, blieben bislang erfolglos. Eine Möglichkeit A zu stabilisieren, und somit eine Kopf-Schwanz-Oligomerisierung zu verhindern, bietet die Koordination einer Lewis-Base (LB) an das Boratom und die Blockierung des freien Elektronenpaares des Phosphoratoms durch Koordination an eine ...

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Translation of the abstract (English)

All attempts to synthesise the parent compound H2P-BH2 A of the large class of phosphanylboranes failed, and only theoretical investigations on A have been performed. A possibility to stabilise A and thereby avoid its head-to-tail oligomerisation, is the coordination of a Lewis-base (LB) to the boron atom and a Lewis-acid (LA) to the lone pair of the phosphorusatom to receive LA/LB-stabilised ...

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