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Cobalt-Mediated [2+2+2] Cycloaddition of Alkynyl Boronates to Indole and Pyrrole Double Bonds

Amslinger, Sabine ; Aubert, Corinne ; Gandon, Vincent ; Malacria, Max ; Paredes, Elisa ; Vollhardt, K. Peter C.


The complex [CpCo(C2H4)2] facilitates the [2+2+2] cycloaddn. of borylalkynes to N-(4-pentynoyl)indole and -pyrrole to furnish heterocyclofused borylcyclohexadienes regioselectively.

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