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Darstellung und Reaktivität von P-H-funktionellen Übergangsmetallcarbonylkomplexen

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Dreher, Cornelia
Date of publication of this fulltext: 04 Jan 2011 11:00

Abstract (German)

In dieser Arbeit gelang durch die Methanolyse von SiMe3-Gruppen zur Darstellung von P–H-funktionellen Übergangsmetallcarbonylkomplexen erstmals die Darstellung der bisher unbekannten Stammverbindungen [(CO)4M(µ-PH2)2M(CO)4-x(PH3)x] (x = 0, M = Cr, W; x = 1, M = W; x = 2, M = W), so wie die Optimierung der bereits bekannten Komplexe des Typs [(CO)6-xW(PH3)x] (x = 2, 3). Durch diese ...


Translation of the abstract (English)

In this work the methanolysis of SiMe3 groups was used as synthetic tool to introduce P–H-functional groups into transition metal carbonyl complexes. Via this synthetic route the novel transition metal complexes with the general stoichiometric composition [(CO)4M(µ-PH2)2M(CO)4-x(PH3)x] (x = 0, M = Cr, W; x = 1, M = W; x = 2, M = W) were prepared. Furthermore, the syntheses of the well established ...


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