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Darstellung und Reaktivität von P-H-funktionellen Übergangsmetallcarbonylkomplexen

Dreher, Cornelia (2011) Darstellung und Reaktivität von P-H-funktionellen Übergangsmetallcarbonylkomplexen. PhD, Universität Regensburg.

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Date of publication of this fulltext: 04 Jan 2011 11:00

Abstract (German)

In dieser Arbeit gelang durch die Methanolyse von SiMe3-Gruppen zur Darstellung von P–H-funktionellen Übergangsmetallcarbonylkomplexen erstmals die Darstellung der bisher unbekannten Stammverbindungen [(CO)4M(µ-PH2)2M(CO)4-x(PH3)x] (x = 0, M = Cr, W; x = 1, M = W; x = 2, M = W), so wie die Optimierung der bereits bekannten Komplexe des Typs [(CO)6-xW(PH3)x] (x = 2, 3). Durch diese ...

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Translation of the abstract (English)

In this work the methanolysis of SiMe3 groups was used as synthetic tool to introduce P–H-functional groups into transition metal carbonyl complexes. Via this synthetic route the novel transition metal complexes with the general stoichiometric composition [(CO)4M(µ-PH2)2M(CO)4-x(PH3)x] (x = 0, M = Cr, W; x = 1, M = W; x = 2, M = W) were prepared. Furthermore, the syntheses of the well established ...

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Item type:Thesis of the University of Regensburg (PhD)
Date:4 January 2011
Referee:Prof. Dr Manfred Scheer and Prof. Dr. Henri Brunner
Date of exam:29 January 2010
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie
Interdisciplinary Subject Network:Not selected
Keywords:Methanolyse, PH3-Ligandkomplexe, zweikernige PH2-verbrückte Übergangsmetallcarbonylkomplexe, single-source-Precursoren, Eisenphosphidnanopartikel, Wolframphosphidnanopartikel, methanolysis, PH3 ligand complexes, transition metal complexes with PH2 bridging ligands, single source precursors, ironphosphide nanoparticles, tungstenphosphide nanoparticles
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:12711
Owner only: item control page

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