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- URN zum Zitieren dieses Dokuments:
- urn:nbn:de:bvb:355-epub-133394
- DOI zum Zitieren dieses Dokuments:
- 10.5283/epub.13339
Zusammenfassung
The photochemistry of the following azide complexes in organic solvents has been investigated: [Au(N3)4]⁻, [Au(N3)2]⁻, [Ag(PPh3)2N3], [Pt(N3)6]2⁻, [Pt(N3)4]2⁻, [Pd(N3)4]2⁻, and [Pd2(N3)6]2⁻. All complexes underwent a photochemical reduction of the metal and oxidation of azide upon ligand to metal charge transfer excitation. The photolysis of the complexes with the metals in the lower oxidation ...
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