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Optical ligand-to-ligand charge transfer of Zn(2,2'-bipyridyl)(3,4-toluenedithiolate)

Benedix, R., Hennig, H., Kunkely, Horst and Vogler, Arnd (1990) Optical ligand-to-ligand charge transfer of Zn(2,2'-bipyridyl)(3,4-toluenedithiolate). Chemical Physics Letters 175, pp. 483-487.

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The electronic structure and the optical ligand-to-ligand charge transfer (LLCT) of the pseudotetrahedral complex Zn (2,2′-bipyridyl) (3,4-toluenedithiolate) is interpreted on the basis of EHT calculations. By comparison with square-planar complexes, it is shown that the extent of electron delocalization between donor and acceptor ligand and charge separation by LLCT excitation depends on the mutual orientation of both ligands.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:13346
Owner only: item control page


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