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Photoluminescence of Tetrameric Silver(I) Complexes

URN to cite this document:
urn:nbn:de:bvb:355-epub-133470
Vogler, Arnd ; Kunkely, Horst
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Date of publication of this fulltext: 15 Mar 2010 06:30


Abstract

The tetrametric complexes [AgP(OCH3)3Cl]4 and [AgP(C6H5)3Cl]4 show an emission which is assigned to a metal-centered 4d-5s transition. This emission occurs at rather low energies (≈ 20800 cm−1) due to modification of the ds transition by metal-metal interaction within the tetrahedral Ag4 moiety of these clusters.


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