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Photochemistry of Tetrasulfido Complexes of Molybdenum(VI), Tungsten(VI), Vanadium(V) and Rhenium(VII)
Vogler, Arnd and Kunkely, Horst (1988) Photochemistry of Tetrasulfido Complexes of Molybdenum(VI), Tungsten(VI), Vanadium(V) and Rhenium(VII). Inorganic Chemistry 27 (3), pp. 504-507.Date of publication of this fulltext: 16 Mar 2010 05:55
Article
DOI to cite this document: 10.5283/epub.13363
Abstract
The tetrasulfido complexes [MoS4]2-, [WS4]2-, [VS4]3-, and [ReS4]- photolyze in solution in the presence of air according to the stoichiometry [MS4]n- + 02 -> [M02S2]n- + S2. The diatomic sulfur can be scavenged by norbornadiene or tetramerizes to yield stable S8. Quantum yields are strongly wavelength-dependent. For all complexes the reactive excited states are of the ligand to metal charge transfer type.
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| Item type | Article | ||||
| Journal or Publication Title | Inorganic Chemistry | ||||
| Publisher: | American Chemical Society | ||||
|---|---|---|---|---|---|
| Volume: | 27 | ||||
| Number of Issue or Book Chapter: | 3 | ||||
| Page Range: | pp. 504-507 | ||||
| Date | 1988 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler | ||||
| Identification Number |
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| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-133635 | ||||
| Item ID | 13363 |
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