Photophysical Properties of Hexanuclear Copper(I) and Silver(I) Clusters

URN to cite this document:: urn:nbn:de:bvb:355-epub-133650
DOI to cite this document:: 10.5283/epub.13365

Sabin, F. ; Ryu, C. K. ; Ford, P. C. ; Vogler, Arnd

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Date of publication of this fulltext: 16 Mar 2010 05:54

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Abstract

The spectroscopic properties, including emission spectra and lifetimes, absorption and diffuse reflectance spectra and excitation spectra, of the hexanuclear copper(I) and silver(I) clusters Cu6(mtc)6 (1), Ag6(mtc) (2), and Ag6(dtc)6 (3) (mtc = di-n-propylmonothiocarbamate, dtc = di-n-propyldithiocarbamate) are reported. At room temperature 1 exhibits a strong single emission (e.g., in toluene ...