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Photochemische Spaltung einer polaren Metall-Metall-Bindung durch Metall zu Metall Charge-Transfer-Anregung von [Ph₃PAu-Co(CO)₄]

URN to cite this document:
urn:nbn:de:bvb:355-epub-133726
DOI to cite this document:
10.5283/epub.13372
Vogler, Arnd ; Kunkely, Horst
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Date of publication of this fulltext: 16 Mar 2010 06:00


Abstract

The polar metal-metal bond of [ Ph3PAuI-Co-I(CO)4 ] was cleaved photochemically by metal to metal ( Co-I -> Au+I) charge transfer excitation. Metallic gold, Ph3P, and [Co2(CO)8] were formed as products.


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