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Photoredox Reaction of Triazidomercurate(II). Generation of Stable Mercury Atoms under Ambient Conditions

URN to cite this document:
urn:nbn:de:bvb:355-epub-133758
DOI to cite this document:
10.5283/epub.13375
Kunkely, Horst ; Vogler, Arnd
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Date of publication of this fulltext: 16 Mar 2010 05:58


Abstract

Upon ligand-to-metal charge-transfer excitation the complex [Hg(N3)3]− in ethanol underwent a photoredox reaction (λirr = 254 nm; Ø = 0.02): [HgII(N3)3]− → Hg0+ 3N2 + N3−. Elemental mercury was released in the form of metal atoms which are stable under ambient conditions.


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