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Electronic Communication in Oligonuclear Ferrocene Complexes with Anionic Four-Coordinate Boron Bridges

Kaufmann, L. ; Breunig, J.-M. ; Vitze, H. ; Schödel, F. ; Nowik, I. ; Pichlmaier, M. ; Bolte, M. ; Lerner, W. ; Winter, Rainer F. ; Herber, R. H. ; Wagner, M.



Abstract

The di- and trinuclear ferrocene species Li[Fc-BPh2-Fc] (Li[9]) and Li-2[Fc-BPh2-fc-BPh2-Fc] (Li-2[10]) have been investigated with regard to their electrochemical properties and the degree of intervalence charge-transfer after partial oxidation. Li[9] shows two distinct one-electron redox waves for its chemically equivalent ferrocenyl substituents in the cyclic voltammogram (E-1/2 = -0.38 V, ...

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