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Photoluminescence of Germanium(II), Tin(II) and Lead(II) Chloride Complexes in Solution
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Nikol, H., Becht, A. and Vogler, Arnd (1992) Photoluminescence of Germanium(II), Tin(II) and Lead(II) Chloride Complexes in Solution. Inorganic Chemistry 31 (15), pp. 3277-3279.DOI to cite this document: 10.5283/epub.13512
Abstract
The absorption and emission spectra of GeC13-, SnC13-, PbC13-, and PbC142- in acetonitrile were recorded. In addition, emission quantum yields and lifetimes were determined. The emitting excited states are of the metalcentered sp type and originate from the 3P state of the free s2 ions. It is suggested that the complex ions which have trigonal-pyramidal C3” (MC13-) and seesaw C2, (PbC1d2-) ...
The absorption and emission spectra of GeC13-, SnC13-, PbC13-, and PbC142- in acetonitrile were recorded. In
addition, emission quantum yields and lifetimes were determined. The emitting excited states are of the metalcentered
sp type and originate from the 3P state of the free s2 ions. It is suggested that the complex ions which have
trigonal-pyramidal C3” (MC13-) and seesaw C2, (PbC1d2-) structures in the ground state rearrange toward trigonalplanar
D3h and tetrahedral Td geometries, respectively, in their sp excited states.
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| Item type | Article | ||||
| Journal or Publication Title | Inorganic Chemistry | ||||
| Publisher | American Chemical Society | ||||
| Volume | 31 | ||||
| Number of Issue or Book Chapter | 15 | ||||
| Page Range | pp. 3277-3279 | ||||
| Date | 1992 | ||||
| Date of publication | 17 Mar 2010 06:11 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler | ||||
| Identification Number |
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| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-135120 | ||||
| Item ID | 13512 |
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