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Photoluminescence of Germanium(II), Tin(II) and Lead(II) Chloride Complexes in Solution
Nikol, H., Becht, A. und Vogler, Arnd (1992) Photoluminescence of Germanium(II), Tin(II) and Lead(II) Chloride Complexes in Solution. Inorganic Chemistry 31 (15), S. 3277-3279.Veröffentlichungsdatum dieses Volltextes: 17 Mrz 2010 06:11
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.13512
Zusammenfassung
The absorption and emission spectra of GeC13-, SnC13-, PbC13-, and PbC142- in acetonitrile were recorded. In addition, emission quantum yields and lifetimes were determined. The emitting excited states are of the metalcentered sp type and originate from the 3P state of the free s2 ions. It is suggested that the complex ions which have trigonal-pyramidal C3” (MC13-) and seesaw C2, (PbC1d2-) ...
The absorption and emission spectra of GeC13-, SnC13-, PbC13-, and PbC142- in acetonitrile were recorded. In
addition, emission quantum yields and lifetimes were determined. The emitting excited states are of the metalcentered
sp type and originate from the 3P state of the free s2 ions. It is suggested that the complex ions which have
trigonal-pyramidal C3” (MC13-) and seesaw C2, (PbC1d2-) structures in the ground state rearrange toward trigonalplanar
D3h and tetrahedral Td geometries, respectively, in their sp excited states.
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| Dokumentenart | Artikel | ||||
| Titel eines Journals oder einer Zeitschrift | Inorganic Chemistry | ||||
| Verlag: | American Chemical Society | ||||
|---|---|---|---|---|---|
| Band: | 31 | ||||
| Nummer des Zeitschriftenheftes oder des Kapitels: | 15 | ||||
| Seitenbereich: | S. 3277-3279 | ||||
| Datum | 1992 | ||||
| Institutionen | Chemie und Pharmazie > Institut für Anorganische Chemie > Entpflichtete oder im Ruhestand befindliche Professoren > Prof. Dr. Arnd Vogler | ||||
| Identifikationsnummer |
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| Dewey-Dezimal-Klassifikation | 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||
| Status | Veröffentlicht | ||||
| Begutachtet | Ja, diese Version wurde begutachtet | ||||
| An der Universität Regensburg entstanden | Ja | ||||
| URN der UB Regensburg | urn:nbn:de:bvb:355-epub-135120 | ||||
| Dokumenten-ID | 13512 |
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