Go to content
UR Home

Electronic Structure and Spectroscopic Properties of Copper Catecholate Complexes with Interligand Charge Transfer Behavior

URN to cite this document:
urn:nbn:de:bvb:355-epub-135647
DOI to cite this document:
10.5283/epub.13564
Benedix, R. ; Vogler, Arnd
[img]
Preview
PDF
(518kB)
Date of publication of this fulltext: 17 Mar 2010 09:03


Abstract

The structural and spectroscopic properties of copper catecholate complexes with nitrogen ligands of the α- diimine type are studied by qualitative MO considerations. The characteristic feature of these donor acceptor systems is an interligand charge-transfer from the catecholate donor to the α-diimine acceptor site. The dependence of the interligand charge-transfer absorption band on the energies of the acceptor and the donor levels as well as on the solvent polarity is discussed.


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: daten@ur.de
0941 943 -5707

Contact persons