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Electronic Structure and Spectroscopic Properties of Copper Catecholate Complexes with Interligand Charge Transfer Behavior

URN to cite this document:
urn:nbn:de:bvb:355-epub-135647
DOI to cite this document:
10.5283/epub.13564
Benedix, R. ; Vogler, Arnd
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Date of publication of this fulltext: 17 Mar 2010 09:03


Abstract

The structural and spectroscopic properties of copper catecholate complexes with nitrogen ligands of the α- diimine type are studied by qualitative MO considerations. The characteristic feature of these donor acceptor systems is an interligand charge-transfer from the catecholate donor to the α-diimine acceptor site. The dependence of the interligand charge-transfer absorption band on the energies of the acceptor and the donor levels as well as on the solvent polarity is discussed.


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