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Electronic Spectra and Photochemistry of Tin(II), Lead(II), antimony(III) and Bismuth(III) Bromide Complexes in Solution

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Oldenburg, K. ; Vogler, Arnd
Date of publication of this fulltext: 17 Mar 2010 09:07


The electronic spectra of bromo complexes of main group metal ions with an s2 electronic configuration (SnBr3-, PbBr3-, PbBr42-, SbBr4-, SbBr63-, BiBr4-, BiBr63-) in acetonitrile long-wavelength absorption bands which are assigned to metal-centered sp transitions. Compared to the corresponding chloro complexes the sp bands of the bromo complexes appear at longer wavelength due to sp/LMCT mixing (LMCT=ligand-to-metal charge transfer)

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