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Electronic Spectra and Photochemistry of Tin(II), Lead(II), antimony(III) and Bismuth(III) Bromide Complexes in Solution
Oldenburg, K. and Vogler, Arnd (1993) Electronic Spectra and Photochemistry of Tin(II), Lead(II), antimony(III) and Bismuth(III) Bromide Complexes in Solution. Zeitschrift für Naturforschung B 48 (11), pp. 1519-1523.Date of publication of this fulltext: 17 Mar 2010 09:07
Article
DOI to cite this document: 10.5283/epub.13569
Abstract
The electronic spectra of bromo complexes of main group metal ions with an s2 electronic configuration (SnBr3-, PbBr3-, PbBr42-, SbBr4-, SbBr63-, BiBr4-, BiBr63-) in acetonitrile long-wavelength absorption bands which are assigned to metal-centered sp transitions. Compared to the corresponding chloro complexes the sp bands of the bromo complexes appear at longer wavelength due to sp/LMCT mixing (LMCT=ligand-to-metal charge transfer)
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Details
| Item type | Article |
| Journal or Publication Title | Zeitschrift für Naturforschung B |
| Volume: | 48 |
|---|---|
| Number of Issue or Book Chapter: | 11 |
| Page Range: | pp. 1519-1523 |
| Date | 1993 |
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Keywords | Anionic complex ; Bromo complex ; Quaternary ammonium compound ; Acetonitrile ; Photochemical reaction ; Charge transfer ; Electron spectrometry ; Bismuth III Complexes ; Lead II Complexes ; Tin II Complexes ; Antimony III Complexes ; Non metal Complexes ; |
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences |
| Status | Published |
| Refereed | Yes, this version has been refereed |
| Created at the University of Regensburg | Yes |
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-135697 |
| Item ID | 13569 |
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