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1,2,3-Triphosphole derivatives as reactive intermediates

DOI to cite this document:
Stubenhofer, Markus ; Kuntz, Christian ; Balázs, Gábor ; Zabel, Manfred ; Scheer, Manfred
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Date of publication of this fulltext: 07 Jun 2010 12:14


The complexes [Cp*E{W(CO)5}2] (E = P, As; Cp* = C5Me5) react with 1,2-diphosphinobenzene to give 1,2,3-triphosphole and 2-arsa-1,3-diphosphole derivatives as reactive intermediates that dimerise to polycyclic phosphorous and arsenic containing cage compounds.

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