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1,2,3-Triphosphole derivatives as reactive intermediates
Stubenhofer, Markus, Kuntz, Christian, Balázs, Gábor, Zabel, Manfred and Scheer, Manfred
(2009)
1,2,3-Triphosphole derivatives as reactive intermediates.
Chemical Communications 2009, pp. 1745-1747.
Date of publication of this fulltext: 07 Jun 2010 12:14
Article
DOI to cite this document: 10.5283/epub.15091
Abstract
The complexes [Cp*E{W(CO)(5)}(2)] (E = P, As; Cp* = C5Me5) react with 1,2-diphosphinobenzene to give 1,2,3-triphosphole and 2-arsa-1,3-diphosphole derivatives as reactive intermediates that dimerise to polycyclic phosphorous and arsenic containing cage compounds.
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| Item type | Article | ||||
| Journal or Publication Title | Chemical Communications | ||||
| Publisher: | ROYAL SOC CHEMISTRY | ||||
|---|---|---|---|---|---|
| Place of Publication: | CAMBRIDGE | ||||
| Volume: | 2009 | ||||
| Page Range: | pp. 1745-1747 | ||||
| Date | 2009 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number |
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| Keywords | DUAL SUPERMESITYL STABILIZATION; PHOSPHORUS TRIPLE BOND; TRANSITION-METAL; TRICOORDINATE PHOSPHORUS; COMPLEXES; CHEMISTRY; GROUP-15; PLANAR; LIGAND; ANION; | ||||
| Dewey Decimal Classification | 600 Technology > 660 Chemical engineering | ||||
| Status | Published | ||||
| Refereed | Unknown | ||||
| Created at the University of Regensburg | Unknown | ||||
| Item ID | 15091 |
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