Scheer, Manfred, Schindler, Andrea, Gröger, Christian, Virovets, Alexander Virovets V. and Peresypkina, Eugenia V. (2009) A spherical molecule with a carbon-free Ih-C80 topological framework [Ein sphärisches Molekül mit einem Kohlenstoff-freien Ih-C80-topologischen Gerüst]. Angewandte Chemie International Edition 48 (27), pp. 5046-5049.
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Abstract
The complete encapsulation of ortho-carborane by a fullerene-like building-block system consisting of pentaphosphaferrocene and CuICl leads to the formation of the spherical supermolecule C2B10H12§[{Cp*Fe(5-P5)}12(CuCl)20]. This product of template-controlled aggregation represents the first example of a carbon-free C80 analogue possessing icosahedral symmetry.
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 7 April 2009 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number: |
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| Keywords: | carborane; fullerenes; phosphorus; self-assembly; supramolecular chemistry | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Unknown | ||||
| Created at the University of Regensburg: | Unknown | ||||
| Item ID: | 15093 |
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