A spherical molecule with a carbon-free Ih-C80 topological framework [Ein sphärisches Molekül mit einem Kohlenstoff-freien Ih-C80-topologischen Gerüst]

DOI to cite this document:: 10.5283/epub.15093

Scheer, Manfred ; Schindler, Andrea ; Gröger, Christian ; Virovets, Alexander V. ; Peresypkina, Eugenia V.

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Date of publication of this fulltext: 07 Jun 2010 12:15

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Abstract

The complete encapsulation of ortho-carborane by a fullerene-like building-block system consisting of pentaphosphaferrocene and CuICl leads to the formation of the spherical supermolecule C2B10H12§[{Cp*Fe(5-P5)}12(CuCl)20]. This product of template-controlled aggregation represents the first example of a carbon-free C80 analogue possessing icosahedral symmetry.

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